Hello,
The evaluation kit is based of an sbRIO-9636, and here is the manual. Page 19, figure 17 shows the pinout and where +5VDC can be supplied. +/- 10V can only be provided from Analog Output (Page 53). Note if you remove the eval daughter board, the functionality cannot be guaranteed when you reconnect it.
Regards
Deborah Burke
NI Hardware and Drivers Product Manager
Certified LabVIEW Architect